Bulk deposition of pesticide mixtures in a Canadian prairie city and the influence of soil temperature fluctuations on 17β-estradiol mineralization

dc.contributor.authorAndronak, Lindsey Amy
dc.contributor.examiningcommitteeBullock, Paul (Soil Science) Lawley, Yvonne (Plant Science)en_US
dc.contributor.supervisorFarenhorst, Annemieke (Soil Science)en_US
dc.date.accessioned2013-08-16T15:04:24Z
dc.date.available2013-08-16T15:04:24Z
dc.date.issued2013-08-16
dc.degree.disciplineSoil Scienceen_US
dc.degree.levelMaster of Science (M.Sc.)en_US
dc.description.abstractTests were conducted for 71 pesticides in weekly bulk (wet + dry) deposition samples collected from May 25 to September 21 over two years at two sites in the City of Winnipeg, Canada. Twenty-one pesticides and their metabolites were detected in this study and 99% of samples collected contained mixtures of two or more pesticides. Malathion and glyphosate were the largest contributors to bulk deposition in 2010 and 2011, respectively. A second study examined the mineralization of 2,4-D and 17β-estradiol using a novel in-field soil microcosm study and a series of laboratory experiments under different temperature incubations. Results indicated that temperature fluctuations do not greatly affect the amount or rate of mineralization relative to the traditionally constant laboratory incubations of 20°C; however long-term freezing of soil reduced potential mineralization over time. This research advances scientific knowledge of agri-chemical fate and provides data for strengthening current environmental policy analysis in Canada.en_US
dc.description.noteOctober 2013en_US
dc.identifier.urihttp://hdl.handle.net/1993/22029
dc.language.isoengen_US
dc.rightsopen accessen_US
dc.subject17β-estradiolen_US
dc.subject2,4-Den_US
dc.subjectmineralizationen_US
dc.subjectin-fielden_US
dc.subjectmicrocosmsen_US
dc.subjectfreezingen_US
dc.subjectrate constanten_US
dc.subjecttemperature fluctuationsen_US
dc.subjectatmospheric depositionen_US
dc.subjectglyphosateen_US
dc.subjectmalathionen_US
dc.titleBulk deposition of pesticide mixtures in a Canadian prairie city and the influence of soil temperature fluctuations on 17β-estradiol mineralizationen_US
dc.typemaster thesisen_US
local.subject.manitobayesen_US
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