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    Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based N^N–^N Pincer Ligands

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    Date
    2020-04-24
    Author
    mandapati, pavan
    Braun, Jason
    Sidhu, Baldeep K
    Wilson, Gabrielle
    Herbert, David E
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    Abstract
    Ni(II) complexes supported by tridentate N^N–^N diarylamido pincer-type ligands have been demonstrated to act as active catalysts in the carbon–carbon bond forming alkylation of azoles using unactivated alkyl halides. Here, we show that benzannulated phenanthridine-containing ligands can form homogeneous Ni(II) catalysts active with both benzoxazole and benzothiazole substrates. These precatalysts have been fully characterized in solution and the solid state, including by cyclic voltammetry.
    URI
    http://hdl.handle.net/1993/36052
    DOI
    10.1021/acs.organomet.0c00161
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    • Faculty of Science Scholarly Works [209]
    • University of Manitoba Scholarship [1978]

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