Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based N^N–^N Pincer Ligands
| dc.contributor.author | mandapati, pavan | |
| dc.contributor.author | Braun, Jason | |
| dc.contributor.author | Sidhu, Baldeep K | |
| dc.contributor.author | Wilson, Gabrielle | |
| dc.contributor.author | Herbert, David E | |
| dc.date.accessioned | 2021-10-22T17:52:05Z | |
| dc.date.available | 2021-10-22T17:52:05Z | |
| dc.date.issued | 2020-04-24 | |
| dc.date.submitted | 2021-10-15T20:00:54Z | en_US |
| dc.description.abstract | Ni(II) complexes supported by tridentate N^N–^N diarylamido pincer-type ligands have been demonstrated to act as active catalysts in the carbon–carbon bond forming alkylation of azoles using unactivated alkyl halides. Here, we show that benzannulated phenanthridine-containing ligands can form homogeneous Ni(II) catalysts active with both benzoxazole and benzothiazole substrates. These precatalysts have been fully characterized in solution and the solid state, including by cyclic voltammetry. | en_US |
| dc.description.sponsorship | Natural Sciences and Engineering Research Council of Canada (RGPIN-2014-03733) | en_US |
| dc.identifier.citation | Organometallics 2020, 39(10), 1989–1997 | en_US |
| dc.identifier.doi | 10.1021/acs.organomet.0c00161 | |
| dc.identifier.other | 0000-0002-2016-6601 | |
| dc.identifier.uri | http://hdl.handle.net/1993/36052 | |
| dc.language.iso | eng | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.rights | open access | en_US |
| dc.subject | Organometallic Catalysis | en_US |
| dc.subject | Coordination Chemistry | en_US |
| dc.title | Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based N^N–^N Pincer Ligands | en_US |
| dc.type | Preprint | en_US |
| local.author.affiliation | Faculty of Science | en_US |