Diiminepyridine-Supported Phosphorus(I) and Phosphorus(III) Complexes: Synthesis, Characterization, and Electrochemistry

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Date
2020-06-08
Authors
Gray, Paul A
Braun, Jason
Rahimi, Naser
Herbert, David E
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley VCH
Abstract
The synthesis of phosphorus coordination complexes of redox non-innocent diiminepyridine (DIP) ligands with the pnictogen in both the P(I) and P(III) oxidation states is presented. Electrochemical characterization indicates the DIP scaffold can retain its ability to act as an electron reservoir when coordinated to main-group elements.
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Keywords
Coordination Chemistry
Citation
European Journal of Inorganic Chemistry 2020, 2105-2111