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dc.contributor.authorMondal, Rajarshi
dc.contributor.authorHerbert, David E
dc.date.accessioned2021-10-22T17:52:54Z
dc.date.available2021-10-22T17:52:54Z
dc.date.issued2020-03-30
dc.date.submitted2021-10-15T20:22:52Zen_US
dc.identifier.citationOrganometallics 2020, 39(8), 1310–1317en_US
dc.identifier.urihttp://hdl.handle.net/1993/36055
dc.description.abstractA ruthenium hydrido chloride complex (1) supported by a simple, heteroleptic bidentate P^N ligand (L1) containing a diarylphosphine and a benzannulated phenanthridine donor arm is reported. In the presence of base, complex 1 catalyzes multicomponent reactions using alcohol precursors to produce structurally diverse molecules including pyridines, quinolines, and pyrimidines via acceptorless dehydrogenative coupling pathways. Notably, L1 does not bear readily (de)protonated Brønsted acidic or basic groups common to transition metal catalysts capable of these sorts of transformations, suggesting metal–ligand cooperativity does not play a significant role in the catalytic reactivity of 1. A rare example of an η2-aldehyde adduct of ruthenium was isolated and structurally characterized, and its role in acceptorless dehydrogenative coupling reactions is discussed.en_US
dc.description.sponsorshipNatural Sciences and Engineering Research Council of Canada (RGPIN-2014-03733)en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsopen accessen_US
dc.subjectOrganometallic Catalysisen_US
dc.titleSynthesis of Pyridines, Quinolines, and Pyrimidines via Acceptorless Dehydrogenative Coupling Catalyzed by a Simple Bidentate P^N Ligand Supported Ru Complexen_US
dc.typePreprinten_US
dc.identifier.doi10.1021/acs.organomet.0c00058
local.author.affiliationFaculty of Scienceen_US


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