Nickel(II), copper(I) and zinc(II) complexes supported by a (4-diphenylphosphino)phenanthridine ligand
| dc.contributor.author | Mondal, Rajarshi | |
| dc.contributor.author | Giesbrecht, Patrick | |
| dc.contributor.author | Herbert, David E | |
| dc.date.accessioned | 2021-10-15T19:41:26Z | |
| dc.date.available | 2021-10-15T19:41:26Z | |
| dc.date.issued | 2016-03-29 | |
| dc.date.submitted | 2021-10-15T19:30:41Z | en_US |
| dc.description.abstract | A synthetic route to 4-bromophenanthridine has been devised, enabling the construction of (4-diphenylphosphino)phenanthridine (1), a heterobifunctional Lewis base containing both phosphine and phenanthridine donors. The coordination chemistry of 1 with ions of late first-row transition metals nickel, copper and zinc has been explored, leading to the isolation and characterization of an organometallic Ni(II) complex, chloro(1-naphthyl)[(4-diphenylphosphino)phenanthridine]nickel (2), a halide-bridged copper(I) complex, bromo[(4-diphenylphosphino)phenanthridine]copper dimer (3), and a Zn(II) complex, bis(chloro)[(4-diphenylphosphino)phenanthridine]zinc (4). The solid-state structures of 2–4 demonstrate the ability of 1 to support both square planar and tetrahedral geometries. Electrochemical and luminescence studies revealed both metal and ligand-based redox activity and emissive properties. | en_US |
| dc.description.sponsorship | Natural Sciences and Engineering Research Council of Canada (RGPIN-2014-03733) | en_US |
| dc.identifier.citation | Polyhedron 2016, 108, 156-162 | en_US |
| dc.identifier.doi | 10.1016/j.poly.2015.10.051 | |
| dc.identifier.uri | http://hdl.handle.net/1993/36047 | |
| dc.language.iso | eng | en_US |
| dc.publisher | Elsevier | en_US |
| dc.rights | open access | en_US |
| dc.subject | Ligand design | en_US |
| dc.title | Nickel(II), copper(I) and zinc(II) complexes supported by a (4-diphenylphosphino)phenanthridine ligand | en_US |
| dc.type | Preprint | en_US |
| local.author.affiliation | Faculty of Science | en_US |