Landfill leachate treatment by waste-derived activated carbon

dc.contributor.authorde Matos Ferraz, Fernanda
dc.contributor.examiningcommitteeHolländer, Hartmut (Civil Engineering) Thiyam-Holländer, Usha (Food and Human Nutritional Sciences)en_US
dc.contributor.supervisorYuan, Qiuyan (Civil Engineering)en_US
dc.date.accessioned2019-11-19T15:59:04Z
dc.date.available2019-11-19T15:59:04Z
dc.date.issued2019-11-12en_US
dc.date.submitted2019-11-17T17:21:22Zen
dc.degree.disciplineCivil Engineeringen_US
dc.degree.levelMaster of Science (M.Sc.)en_US
dc.description.abstractThis research evaluated the use of spent coffee grounds (SCG) and oat hulls as precursors for activated carbon applied for organic matter removal from leachate, a pollutant wastewater produced by landfills. These precursors were selected based on their global commercial significance. The high demand for the beverage coffee is directly proportional to the generation of SCG as organic waste. Similarly, oat is a popular cereal consumed worldwide, and its industrial processing generates hulls as organic waste. The activated carbon samples were produced by chemical activation with phosphoric acid (H3PO4), using distinct impregnation ratios: 50 and 100 % for SCG, and 60 and 100 % for oat hulls; followed by pyrolysis in an inert atmosphere, at 350 and 500 °C. The feasibility of the tested precursors as adsorbents was initially assessed in experiments with synthetic leachate. Afterwards, the results from the initial tests were compared with those obtained in real leachate treatment. The studies described in this thesis showed that the impregnation ratios and pyrolysis temperatures interfered with the surface areas of the formed adsorbents, consequently affecting the organic matter removal from leachate. Both oat hulls and SCG were successfully recovered as activated carbon, and efficiently treated synthetic and real leachate, removing more than 90 % of the organic matter. Therefore, this study highly encourages the use of SCG and oat hulls as precursors for activated carbon production and their application to treat leachate.en_US
dc.description.noteFebruary 2020en_US
dc.identifier.urihttp://hdl.handle.net/1993/34376
dc.language.isoengen_US
dc.rightsopen accessen_US
dc.subjectActivated carbonen_US
dc.subjectLandfill leachateen_US
dc.subjectAdsorptionen_US
dc.subjectSpent coffee groundsen_US
dc.subjectOat hullsen_US
dc.subjectOrganic matter removalen_US
dc.titleLandfill leachate treatment by waste-derived activated carbonen_US
dc.typemaster thesisen_US
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