Bio-polymeric materials for electrical insulation applications.

dc.contributor.authorWarnakulasooriya, Lakshan
dc.contributor.examiningcommitteeKordi, Behzad (Electrical and Computer Engineering)en_US
dc.contributor.examiningcommitteeLevin, David (Biosystems Engineering)en_US
dc.contributor.supervisorOliver, Derek (Electrical and Computer Engineering)en_US
dc.date.accessioned2022-02-04T21:07:41Z
dc.date.available2022-02-04T21:07:41Z
dc.date.copyright2022-02-04
dc.date.issued2022-01-17en_US
dc.date.submitted2022-02-04T19:30:52Zen_US
dc.degree.disciplineElectrical and Computer Engineeringen_US
dc.degree.levelMaster of Science (M.Sc.)en_US
dc.description.abstractFossil-fuel-based insulation materials such as polyvinyl chloride (PVC), low-density polyethylene (LDPE), cross-linked polyethylene (XLPE) and ethylene-vinyl acetate (EVA) have dominated the electrical insulation industry at present. Increased use of these polymers have caused a serious threat to environment causing, environmental pollution, global warming, and climate changes worldwide. Biopolymers offers a solution to these problems, since they are fully renewable from bio-sources such as biomass, agricultural by-products, and biological waste. In order to utilize biopolymers as an electrical insulation material, they should match or exceed electrical, mechanical, and thermal properties of their fossil-fuel-based counterparts. Four bio-polymers namely polyhydroxy butyrate (PHB), poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), poly (lactic acid) (PLA), cellulose acetate (CA) and three fossil-fuel-based synthetic polymers polycaprolactone (PCL), polybutylene succinate (PBS), poly (butylene adipate-co-terephthalate) (PBAT) are selected based on their popularity in research and commercial availability. Although commercial manufacturing of these four synthetic polymers is from fossil-fuel-based sources, they can be synthesised from bio-sources as well. Samples of six of these selected polymers, PHB, PHBV, PCL, PBS, and PBAT are obtained collaborating with the Biosystems Engineering department for the electrical measurements. These samples are thin films, prepared from spin-casting process. Electrical properties such as complex dielectric constant, volume resistivity and AC electrical breakdown strength of these samples are measured, while thermal and mechanical properties are summarized from literature. Using experimental measurements and the literature data, properties of these selected polymers are compared with conventional polymers such as PVC, LDPE, XLPE and EVA. Few biopolymers are shortlisted as possible candidate materials for electrical insulation applications.en_US
dc.description.noteMarch 2022en_US
dc.identifier.urihttp://hdl.handle.net/1993/36280
dc.language.isoengen_US
dc.rightsopen accessen_US
dc.subjectFossil-fuel-based polymers, Bio-polymers, Electrical insulation materials, Renewable polymers, Synthetic polymers, Complex dielectric constant, Volume resistivity, AC electrical breakdown strength.en_US
dc.titleBio-polymeric materials for electrical insulation applications.en_US
dc.typemaster thesisen_US
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