Redox non-innocent bis(2,6-diimine-pyridine) ligand–iron complexes as anolytes for flow battery applications
| dc.contributor.author | Duarte, Gabriel | |
| dc.contributor.author | Braun, Jason | |
| dc.contributor.author | Giesbrecht, Patrick | |
| dc.contributor.author | Herbert, David E | |
| dc.date.accessioned | 2021-10-22T17:51:21Z | |
| dc.date.available | 2021-10-22T17:51:21Z | |
| dc.date.issued | 2017-11-13 | |
| dc.date.submitted | 2021-10-15T19:53:50Z | en_US |
| dc.description.abstract | Diiminepyridines are a well-known class of “non-innocent” ligands that confer additional redox activity to coordination complexes beyond metal-centred oxidation/reduction. Here, we demonstrate that metal coordination complexes (MCCs) of diiminepyridine (DIP) ligands with iron are suitable anolytes for redox-flow battery applications, with enhanced capacitance and stability compared with bipyridine analogs, and access to storage of up to 1.6 electron equivalents. Substitution of the ligand is shown to be a key factor in the cycling stability and performance of MCCs based on DIP ligands, opening the door to further optimization. | en_US |
| dc.description.sponsorship | Natural Sciences and Engineering Research Council of Canada (RGPIN-2014-03733) | en_US |
| dc.identifier.citation | Dalton Transactions, 2017, 46, 16439-16445 | en_US |
| dc.identifier.doi | 10.1039/C7DT03915H | |
| dc.identifier.uri | http://hdl.handle.net/1993/36050 | |
| dc.language.iso | eng | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.rights | open access | en_US |
| dc.subject | flow battery anolytes | en_US |
| dc.subject | Coordination Chemistry | en_US |
| dc.title | Redox non-innocent bis(2,6-diimine-pyridine) ligand–iron complexes as anolytes for flow battery applications | en_US |
| dc.type | Preprint | en_US |
| local.author.affiliation | Faculty of Science | en_US |