Physical and biological controls on ocean acidification in the Southampton Island region, Hudson Bay

dc.contributor.authorYezhova, Yekaterina
dc.contributor.examiningcommitteeMundy, CJ (Environment & Geography)en_US
dc.contributor.examiningcommitteeEhn, Jens (Environment & Geography)en_US
dc.contributor.examiningcommitteeKuzyk, Zou Zou (Earth Sciences)en_US
dc.contributor.supervisorPapakyriakou, Tim
dc.date.accessioned2023-04-27T14:12:35Z
dc.date.available2023-04-27T14:12:35Z
dc.date.copyright2023-03-22
dc.date.issued2023-03-22
dc.date.submitted2023-03-22T15:59:59Zen_US
dc.degree.disciplineEnvironment and Geographyen_US
dc.degree.levelMaster of Science (M.Sc.)en_US
dc.description.abstractLocated in northwestern Hudson Bay, the Southampton Island region was identified as an Ecologically and Biologically Significant Area by Fisheries and Oceans Canada, and most recently distinguished as an Area of Interest in 2019 to become a Marine Protected Area. The region is undergoing climate-related changes; however, its oceanography has received little attention until recently. The main goal of this thesis was to provide a baseline evaluation of the state of ocean acidification of these waters, and to identify key factors driving changes in both pH and calcium carbonate saturation state. Twenty-two stations were sampled around the Island in August of 2019 for salinity, stable oxygen isotope ratio of seawater, total alkalinity, dissolved inorganic carbon (DIC), and stable carbon isotope ratio of DIC (δ13CDIC), providing comprehensive water column coverage. High fractions of sea-ice melt were found in surface waters in Foxe Basin/Channel, which had experienced the most recent loss of sea ice. High fractions of meteoric water were found in near-surface waters in Roes Welcome Sound, likely from Wager Bay outflow, and south of the Island, likely from both rivers local to the Island and from Hudson Bay’s northwestern rivers. Regionally high pH, low pCO2, dissolved oxygen (O2) oversaturation, and enriched values of δ13CDIC, and thus likely areas of net primary production, were generally observed in the top ~50 m in Foxe Basin/Channel and Roes Welcome Sound, and near surface in Repulse Bay and Frozen Strait. More acidic and aragonite-undersaturated waters, potentially corrosive to marine calcifying organisms, were found below ~60 to 250 m at stations in Foxe Basin/Channel, and in bottom waters of South Bay and Evans Strait. These areas were high in pCO2 and undersaturated in O2, signifying net respiration had likely produced the observed values. It was concluded that while primary production and respiration appeared to be the dominant processes controlling the concentration of DIC in the Southampton Island region, the data could not be explained by any single process alone, highlighting the importance of metabolic processes, freshwater inputs, and air-sea gas exchange in governing the DIC pool in the region.en_US
dc.description.noteMay 2023en_US
dc.identifier.urihttp://hdl.handle.net/1993/37296
dc.language.isoengen_US
dc.rightsopen accessen_US
dc.subjectSouthampton Islanden_US
dc.subjectHudson Bayen_US
dc.subjectOcean acidificationen_US
dc.subjectCarbonen_US
dc.subjectStable isotopesen_US
dc.titlePhysical and biological controls on ocean acidification in the Southampton Island region, Hudson Bayen_US
dc.typemaster thesisen_US
local.subject.manitobanoen_US
oaire.awardNumber553712-2020en_US
oaire.awardTitleAlexander Graham Bell Canada Graduate Scholarships - Master'sen_US
oaire.awardURIhttps://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=704748en_US
project.funder.identifierhttps://doi.org/10.13039/501100000038en_US
project.funder.nameNatural Sciences and Engineering Research Council of Canadaen_US
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