P–C Bond Activation and Transfer of a Diphenylphosphino Unit from 1,1′-Bis(diphenylphosphino)ferrocene: Unexpected Templated Synthesis of an N^N–^P Pincer Ligand Palladium Complex
| dc.contributor.author | Sidhu, Baldeep K | |
| dc.contributor.author | Braun, Jason | |
| dc.contributor.author | Herbert, David E | |
| dc.date.accessioned | 2021-10-15T19:23:58Z | |
| dc.date.available | 2021-10-15T19:23:58Z | |
| dc.date.issued | 2021-07-26 | |
| dc.date.submitted | 2021-10-15T19:14:54Z | en_US |
| dc.description.abstract | The Pd-catalyzed Buchwald–Hartwig amination of 2-bromo-1-iodobenzene with (4-amino-2-tert-butyl)phenanthridine using 1,1′-bis(diphenylphosphino)ferrocene (dppf) results in a side reaction involving the first reported example of P–C bond activation of dppf and the templated formation of an N∧N–∧P-supported Pd(II) coordination complex. The full characterization of this complex along with a proposed mechanism for a rare example of unstrained P–C(cyclopentadienyl) bond activation are described. | en_US |
| dc.description.sponsorship | Natural Sciences and Engineering Research Council Discovery Grant (RGPIN-2014-03733) | en_US |
| dc.identifier.citation | Organometallics 2021, 40(15), 2538-2545 | en_US |
| dc.identifier.doi | 10.1021/acs.organomet.1c00277 | |
| dc.identifier.other | 0000-0001-8190-2468 | |
| dc.identifier.other | 0000-0002-2016-6601 | |
| dc.identifier.uri | http://hdl.handle.net/1993/36045 | |
| dc.language.iso | eng | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.rights | open access | en_US |
| dc.subject | Coordination Chemistry | en_US |
| dc.subject | Organometallic Catalysis | en_US |
| dc.title | P–C Bond Activation and Transfer of a Diphenylphosphino Unit from 1,1′-Bis(diphenylphosphino)ferrocene: Unexpected Templated Synthesis of an N^N–^P Pincer Ligand Palladium Complex | en_US |
| dc.type | Preprint | en_US |
| local.author.affiliation | Faculty of Science | en_US |