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dc.contributor.authorMondal, Rajarshi
dc.contributor.authorLozada, Issiah
dc.contributor.authorStotska, Olha
dc.contributor.authorHerbert, David E
dc.date.accessioned2021-10-22T17:56:08Z
dc.date.available2021-10-22T17:56:08Z
dc.date.issued2020-10-23
dc.date.submitted2021-10-16T18:32:12Zen_US
dc.identifier.citationJ. Org. Chem. 2020, 85(21), 13747–13756en_US
dc.identifier.urihttp://hdl.handle.net/1993/36065
dc.description.abstractA simple catalytic synthesis of luminescent pyrimidines from benzamidines and alcohols is reported. These one-pot, acceptor-less dehydrogenative coupling reactions are catalyzed by a ruthenium hydrido chloride complex (1), supported by a chelating P^N ligand (L1) bearing a benzannulated phenanthridine donor arm. The pyrimidines thus produced are emissive in solution, with photoluminescence quantum yields reaching 72%. Details of the catalytic synthesis and characterization of the pyrimidines in both solution and the solid state are reported, along with computational modeling of the emissive excited states of representative examples.en_US
dc.description.sponsorshipNatural Sciences and Engineering Research Council of Canada (RGPIN-2014-03733)en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsopen accessen_US
dc.subjectOrganometallic Catalysisen_US
dc.titleCatalytic Synthesis of Luminescent Pyrimidines via Acceptor-less Dehydrogenative Couplingen_US
dc.typePreprinten_US
dc.identifier.doi10.1021/acs.joc.0c01882
local.author.affiliationFaculty of Scienceen_US


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