Now showing items 1-4 of 4
Exploiting synergy between ligand design and counterion interactions to boost room temperature phosphorescence from Cu(i) compounds
(Royal Society of Chemistry, 2019-01-16)
The structural and photophysical properties of three sets of luminescent copper complexes of the form [(P^N)2Cu]X are presented. Here, P^N represents a bidentate ligand based on phenanthridine (3,4-benzoquinoline) incorporating ...
Monomeric zinc(II) amide complexes supported by bidentate, benzannulated phenanthridine amido ligands
The first examples of homoleptic zinc amides (1-Zn and 2-Zn) supported by chelating, benzannulated 4-amidophenanthridine ligands (L1, L2) are reported. The organometallic compounds were characterized fully both in solution ...
Luminescent Platinum(II) Complexes of N^N–^N Amido Ligands with Benzannulated N-Heterocyclic Donor Arms: Quinolines Offer Unexpectedly Deeper Red Phosphorescence than Phenanthridines
(American Chemical Society, 2019-10-22)
A platform for investigating the impact of π-extension in benzannulated, anionic pincer-type N^N–^N-coordinating amido ligands and their Pt(II) complexes is presented. Based on bis(8-quinolinyl)amine, symmetric and asymmetric ...
Iron(II) Coordination Complexes with Panchromatic Absorption and Nanosecond Charge-Transfer Excited State Lifetimes
(Nature Publishing Group, 2019-11-18)
Replacing current benchmark rare-element photosensitizers with ones based on abundant and low-cost metals such as iron would help facilitate the large-scale implementation of solar energy conversion. To do so, the ability ...