Electrochemical hydrogenation of a benzannulated pyridine to a dihydropyridine in acidic solution

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dc.contributor.authorGiesbrecht, Patrick
dc.contributor.authorNemez, Dion
dc.contributor.authorHerbert, David E
dc.date.accessioned2021-10-22T17:53:29Z
dc.date.available2021-10-22T17:53:29Z
dc.date.issued2017-11-30
dc.date.submitted2021-10-15T20:42:08Zen_US
dc.description.abstractThe electrochemistry of pyridines in acidic solution is dominated by a ‘weak acid’ reduction on the cyclic voltammetry timescale. Here we show that electrochemical hydrogenation of a benzannulated pyridine, phenanthridine (1), to the biomimetic hydride donor 1,2-dihydrophenanthridine (1-H2) can occur selectively at glassy carbon electrodes over longer timescales of potentiostatic electrolysis.en_US
dc.description.sponsorshipNatural Sciences and Engineering Research Council of Canada (RGPIN-2014-03733)en_US
dc.identifier.citationChemical Communications, 2018, 54, 338-341en_US
dc.identifier.doiDOI https://doi.org/10.1039/C7CC07907A
dc.identifier.urihttp://hdl.handle.net/1993/36057
dc.language.isoengen_US
dc.publisherRoyal Society of Chemistryen_US
dc.rightsopen accessen_US
dc.subjectelectrochemistryen_US
dc.titleElectrochemical hydrogenation of a benzannulated pyridine to a dihydropyridine in acidic solutionen_US
dc.typePreprinten_US
local.author.affiliationFaculty of Scienceen_US
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