Electrochemical hydrogenation of a benzannulated pyridine to a dihydropyridine in acidic solution
dc.contributor.author | Giesbrecht, Patrick | |
dc.contributor.author | Nemez, Dion | |
dc.contributor.author | Herbert, David E | |
dc.date.accessioned | 2021-10-22T17:53:29Z | |
dc.date.available | 2021-10-22T17:53:29Z | |
dc.date.issued | 2017-11-30 | |
dc.date.submitted | 2021-10-15T20:42:08Z | en_US |
dc.description.abstract | The electrochemistry of pyridines in acidic solution is dominated by a ‘weak acid’ reduction on the cyclic voltammetry timescale. Here we show that electrochemical hydrogenation of a benzannulated pyridine, phenanthridine (1), to the biomimetic hydride donor 1,2-dihydrophenanthridine (1-H2) can occur selectively at glassy carbon electrodes over longer timescales of potentiostatic electrolysis. | en_US |
dc.description.sponsorship | Natural Sciences and Engineering Research Council of Canada (RGPIN-2014-03733) | en_US |
dc.identifier.citation | Chemical Communications, 2018, 54, 338-341 | en_US |
dc.identifier.doi | DOI https://doi.org/10.1039/C7CC07907A | |
dc.identifier.uri | http://hdl.handle.net/1993/36057 | |
dc.language.iso | eng | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.rights | open access | en_US |
dc.subject | electrochemistry | en_US |
dc.title | Electrochemical hydrogenation of a benzannulated pyridine to a dihydropyridine in acidic solution | en_US |
dc.type | Preprint | en_US |
local.author.affiliation | Faculty of Science | en_US |