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Now showing items 11-16 of 16
Phenanthridine-Containing Pincer-like Amido Complexes of Nickel, Palladium, and Platinum
(American Chemical Society, 2017-03-07)
Proligands based on bis(8-quinolinyl)amine (L1) were prepared containing one (L2) and two (L3) benzo-fused N-heterocyclic phenanthridinyl (3,4-benzoquinolinyl) units. Taken as a series, L1–L3 provides a ligand template for ...
P–C Bond Activation and Transfer of a Diphenylphosphino Unit from 1,1′-Bis(diphenylphosphino)ferrocene: Unexpected Templated Synthesis of an N^N–^P Pincer Ligand Palladium Complex
(American Chemical Society, 2021-07-26)
The Pd-catalyzed Buchwald–Hartwig amination of 2-bromo-1-iodobenzene with (4-amino-2-tert-butyl)phenanthridine using 1,1′-bis(diphenylphosphino)ferrocene (dppf) results in a side reaction involving the first reported example ...
Monofunctional platinum(ii) anticancer complexes based on multidentate phenanthridine-containing ligand frameworks
(Royal Society of Chemistry, 2020-04-20)
Phenanthriplatin is a leading preclinical anticancer Pt complex distinguished by a phenanthridine ligand that facilitates DNA-targeted covalent binding via intercalation. We report here that Pt(II) complexes incorporating ...
Group VIII coordination complexes of bidentate P^N ligands bearing π-extended quinoline or phenanthridine N-heterocycles
(Royal Society of Chemistry, 2021-02-09)
A series of Fe and Ru coordination complexes supported by bidentate P^N ligands bearing π-extended phenanthridine (3,4-benzoquinoline; PhenLR,R') or quinoline (QuinLH,Ph) N-heterocycles have been synthesized and fully ...
Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based N^N–^N Pincer Ligands
(American Chemical Society, 2020-04-24)
Ni(II) complexes supported by tridentate N^N–^N diarylamido pincer-type ligands have been demonstrated to act as active catalysts in the carbon–carbon bond forming alkylation of azoles using unactivated alkyl halides. Here, ...
Iron(II) Coordination Complexes with Panchromatic Absorption and Nanosecond Charge-Transfer Excited State Lifetimes
(Nature Publishing Group, 2019-11-18)
Replacing current benchmark rare-element photosensitizers with ones based on abundant and low-cost metals such as iron would help facilitate the large-scale implementation of solar energy conversion. To do so, the ability ...