Now showing items 1-6 of 6
In Pursuit of Panchromatic Absorption in Metal Coordination Complexes: Experimental Delineation of the HOMO Inversion Model Using Pseudo-Octahedral Complexes of Diarylamido Ligands
(American Chemical Society, 2020-11-23)
The ability of a compound to broadly absorb light across the incident solar spectrum is an important design target in the development of molecular photosensitizers. The ‘HOMO inversion’ model predicts that for [(tpy)2Fe]2+ ...
Zn-Templated synthesis of substituted (2,6-diimine)pyridine proligands and evaluation of their iron complexes as anolytes for flow battery applications
(Royal Society of Chemistry, 2020-04-13)
Pseudo-octahedral iron complexes supported by tridentate N^N^N-binding, redox ‘non-innocent’ diiminepyridine (DIP) ligands exhibit multiple reversible ligand-based reductions that suggest the potential application of these ...
Electrochemical hydrogenation of α-ketoesters and benzoxazinones using carbon electrodes and a sustainable Brønsted acid
(Royal Society of Chemistry, 2020-11-26)
The direct electrochemical hydrogenation of unsaturated organic compounds containing C[double bond, length as m-dash]N and C[double bond, length as m-dash]O bonds using glassy carbon electrodes and a widely available ...
P–C Bond Activation and Transfer of a Diphenylphosphino Unit from 1,1′-Bis(diphenylphosphino)ferrocene: Unexpected Templated Synthesis of an N^N–^P Pincer Ligand Palladium Complex
(American Chemical Society, 2021-07-26)
The Pd-catalyzed Buchwald–Hartwig amination of 2-bromo-1-iodobenzene with (4-amino-2-tert-butyl)phenanthridine using 1,1′-bis(diphenylphosphino)ferrocene (dppf) results in a side reaction involving the first reported example ...
Group VIII coordination complexes of bidentate P^N ligands bearing π-extended quinoline or phenanthridine N-heterocycles
(Royal Society of Chemistry, 2021-02-09)
A series of Fe and Ru coordination complexes supported by bidentate P^N ligands bearing π-extended phenanthridine (3,4-benzoquinoline; PhenLR,R') or quinoline (QuinLH,Ph) N-heterocycles have been synthesized and fully ...
Catalytic Synthesis of Donor-Acceptor-Donor (D-A-D) and Donor-Acceptor-Acceptor (D-A-A) Pyrimidine-Ferrocenes via Acceptorless Dehydrogenative Coupling: Synthesis, Structures, and Electronic Communication
(American Chemical Society, 2021-06-02)
The synthesis and full characterization of a series of ferrocene-decorated pyrimidines with donor-acceptor-donor (D-A-D) and donor-acceptor-acceptor (D-A-A) architectures are reported. The three novel compounds share a ...