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    Diiminepyridine-Supported Phosphorus(I) and Phosphorus(III) Complexes: Synthesis, Characterization, and Electrochemistry

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    herbert_david MS-024 2020.pdf (4.932Mb)
    Date
    2020-06-08
    Author
    Gray, Paul A
    Braun, Jason
    Rahimi, Naser
    Herbert, David E
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    Abstract
    The synthesis of phosphorus coordination complexes of redox non-innocent diiminepyridine (DIP) ligands with the pnictogen in both the P(I) and P(III) oxidation states is presented. Electrochemical characterization indicates the DIP scaffold can retain its ability to act as an electron reservoir when coordinated to main-group elements.
    URI
    http://hdl.handle.net/1993/36068
    DOI
    10.1002/ejic.202000250
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    • Faculty of Science Scholarly Works [209]
    • University of Manitoba Scholarship [1978]

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