Diiminepyridine-Supported Phosphorus(I) and Phosphorus(III) Complexes: Synthesis, Characterization, and Electrochemistry

Abstract

The synthesis of phosphorus coordination complexes of redox non-innocent diiminepyridine (DIP) ligands with the pnictogen in both the P(I) and P(III) oxidation states is presented. Electrochemical characterization indicates the DIP scaffold can retain its ability to act as an electron reservoir when coordinated to main-group elements.