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dc.contributor.authorMondal, Rajarshi
dc.contributor.authorOrtiz, Robert J
dc.contributor.authorBraun, Jason
dc.contributor.authorHerbert, David E
dc.date.accessioned2021-10-22T17:56:31Z
dc.date.available2021-10-22T17:56:31Z
dc.date.issued2020-11-12
dc.date.submitted2021-10-17T00:48:18Zen_US
dc.identifier.citationCanadian Journal of Chemistry 2021, 99, 245-252en_US
dc.identifier.urihttp://hdl.handle.net/1993/36066
dc.description.abstractAn N-heterocyclic carbene ligand precursor bearing a π-extended phenanthridine (3,4-benzoquinoline) unit is presented. The proligand was isolated as the imidazolium salt of chloride (1•HCl), bromide (1•HBr), or hexafluorophosphate (1•HPF6) counterions. These salts can be deprotonated and the carbene installed on silver centres using Ag2O as both a base and a source of metal ion. The resulting Ag(I) complex (1)AgCl can be used in a transmetalation reaction to generate a Pd(II) coordination complex (1)Pd(CH3CN)Cl2. The characterization and photophysical properties of these complexes is presented, along with a demonstration of the utility of (1)Pd(CH3CN)Cl2 in mediating a catalytic C-N cross-coupling reaction for the preparation of the pharmaceutical Piribedil.en_US
dc.description.sponsorshipNatural Sciences and Engineering Research Council of Canada (RGPIN-2014-03733)en_US
dc.language.isoengen_US
dc.publisherCanadian Science Publishingen_US
dc.rightsopen accessen_US
dc.subjectCoordination Chemistryen_US
dc.titleSynthesis, Characterization and Coordination Chemistry of a Phenanthridine-Containing N-Heterocyclic Carbene Liganden_US
dc.typePreprinten_US
dc.identifier.doi10.1139/cjc-2020-0333
local.author.affiliationFaculty of Scienceen_US


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