Chemical characterization of phosphate diffusion in a multi-ionic environment

dc.contributor.authorOlatuyi, Solomon Olalekan
dc.contributor.examiningcommitteeFlaten, Don (Soil Science) Hunter, Norman (Chemistry)en
dc.contributor.supervisorAkinremi, O. Oluwole (Soil Science)en
dc.date.accessioned2006-09-12T19:02:01Z
dc.date.available2006-09-12T19:02:01Z
dc.date.issued2007-09-12T19:02:01Z
dc.degree.disciplineSoil Scienceen_US
dc.degree.levelMaster of Science (M.Sc.)en_US
dc.description.abstractLow phosphate fertilizer efficiency in high pH soils is primarily due to the retardation of P movement in the soil-P fertilizer reaction zone. The objective of this study was to obtain fundamental information on the influence of multi-ionic interactions on the solubility and diffusion of P in columns containing a model soil system and two soil types. The study also aimed to identify the salt combinations and factors that have the potential to enhance the solubility and movement of P in calcareous soil condition. The results showed that the interaction of NH4+ and SO42- was consistent at enhancing the water solubility and movement of P under a high soil pH condition. This effect was attributed to the combination of various mechanistic factors associated with (NH4)2SO4 compound including significant pH reduction, cation exchange reaction of NH4+ with the exchangeable Ca2+, and anionic competition of SO42- with P for precipitation with Ca2+.en
dc.description.noteOctober 2006en
dc.format.extent1485715 bytes
dc.format.mimetypeapplication/pdf
dc.identifier.urihttp://hdl.handle.net/1993/277
dc.language.isoengen_US
dc.rightsopen accessen_US
dc.subjectphosphateen
dc.subjectdiffusionen
dc.subjectprecipitationen
dc.subjectsolubilityen
dc.subjectresinen
dc.subjectcolumnsen
dc.titleChemical characterization of phosphate diffusion in a multi-ionic environmenten
dc.typemaster thesisen_US
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