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P–C Bond Activation and Transfer of a Diphenylphosphino Unit from 1,1′-Bis(diphenylphosphino)ferrocene: Unexpected Templated Synthesis of an N^N–^P Pincer Ligand Palladium Complex
(American Chemical Society, 2021-07-26)
The Pd-catalyzed Buchwald–Hartwig amination of 2-bromo-1-iodobenzene with (4-amino-2-tert-butyl)phenanthridine using 1,1′-bis(diphenylphosphino)ferrocene (dppf) results in a side reaction involving the first reported example ...