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Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based N^N–^N Pincer Ligands
(American Chemical Society, 2020-04-24)
Ni(II) complexes supported by tridentate N^N–^N diarylamido pincer-type ligands have been demonstrated to act as active catalysts in the carbon–carbon bond forming alkylation of azoles using unactivated alkyl halides. Here, ...
P–C Bond Activation and Transfer of a Diphenylphosphino Unit from 1,1′-Bis(diphenylphosphino)ferrocene: Unexpected Templated Synthesis of an N^N–^P Pincer Ligand Palladium Complex
(American Chemical Society, 2021-07-26)
The Pd-catalyzed Buchwald–Hartwig amination of 2-bromo-1-iodobenzene with (4-amino-2-tert-butyl)phenanthridine using 1,1′-bis(diphenylphosphino)ferrocene (dppf) results in a side reaction involving the first reported example ...